MARCANTONI RESEARCH GROUP
                                            
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Publications

2000 - Present

• G. Bartoli, R. Cipolletti, G. Di Antonio, R. Giovannini, S. Lanari, M. Marcolini, E. Marcantoni: Regio- and Stereocontrolled Hydroiodination of Alkynes Promoted by the Cerium (III) Chloride Heptahydrate/Sodium Iodide System: A Convergent Approach to (R)-Tiagabine. Org. Biomol. Chem. 2010, 8, 3509.
• D. Fiorini, S. Giuli, E. Marcantoni, L.Quissinti, E. Bramucci, C. Amantini, G. Santoni F. Buonanno, C. Ortenzi: A. Straigtforward Diastereoselective Synthesis and Evaluation of Climacostol, a Natural Product with Anticancer activities. Synthesis 2010, 1550.
• G. Bartoli, M. Marcolini, L. Sambri . E. Marcantoni: Applications of CeCl3 as Enviromental Friendly Promoter in Organic Chemistry. Chem. Rev. 2010, 110, 6104.
• G. di Antonio, R. Fiocchi, S. Giuli, M. Marcolini, E. Marcantoni: Synthesis of (R)-Garner type Aldeyde from L-Serine: Useful Building Block for a Furanomycin's Derivative. Synthesis 2009, 951.
• F. Fraschetti, F. R. Novara, A. Filippi, M. Speranza, N. A. Trout, W. Adcock, E.Marcantoni, G. Roselli, M. Marcolini. "Gas-Phase Facial Diastereoselective of Equatorial and Axial 4-Chloroadamant-2-yl Cations" Arkivoc 2009, 74, 5135.
• A.Giardini, F. Rondino, A .Paldini, M. Satta, G, Catenacci, S. Piccirillo, G. Villani, E. Marcantoni, G. Renzi. G. Rosselli, M. Speranza: Host Guest Interaction of Organofluorine Complexes Investigated trough Laser Metodologies: Sensor Lett. 2008, 6, 490.
• R. Ballini, E. Marcantoni, M. Petrini: NItroalkenes as Amination Tools. In Amino Group Chemistry . From Synthesis to the Life Sciences. Ricci A. Ed. Wiley-VCH . Weinheim 2008,93.
• L.Barboni, S.Giuli, A. Filippi, C. Franchetti, M. Marcolini, E. Marcantoni "Substituent Stereochemistry Effects on Diastereoselective Methylation of 4-Chloroadamant-2-ones.Tetrahedron Lett. 2008, 49, 6065.
• G. Bartoli, G. Di Antonio, S. Giuli, E. Marcantoni, M. Marcolini, M. Paoletti "The CeCl3.7H2O-NaI-SiO2 as Efficient Promoter for Friedel-Crafts Reaction of Indoles to Nitroalkenes in Solvent-free Conditions" Synthesis 2007 , 320.
• G, Bartoli, M. Bosco, A. Carlone, R. Dalpozzo, E. Marcantoni. P. Melchiorre, L. Sambri: Reaction of Dicarbonate With Caboxylic Acids catalized Weak Lewis Acids: General Methods for the Synthesis of Anhydride and Esters. Synthesis 2007, 3489.
• G. Bartoli, G. Di Antonio, R. Giovannini , S. Giuli, S. Lanari, M. Paoletti and E. Marcantoni "Efficient Trasformation of Azides to Primary Amines Using the Mild and Easily Accessible CeCl3.7H2O/NaI System. J. Org. Chem. 2008, 73, 1919-1924.
• G. Bartoli, J. G. Fernandèz Bolanos, G. Di Antonio, G. Foglia, S. Giuli, R. Gunnella, M. Mancinelli, E. Marcantoni, M. Paoletti "SiO2 Supported- CeCl3.7H2O/NaI Lewis Acid Promoter: Investigation into the Garcia Gonzalez Reaction in Solvent-free Conditions" J. Org. Chem. 2007, 72, 6029.
• A. Filippi, A. Giardini, E. Marcantoni , A. Paldini, S. Piccirillo, G. Renzi, F. Rondino, G.Rosselli, M. Satta, M. Speranza: Dissymetric effects on the laser spectroscpopy for supersonically expanded rare gas/chiral arene heteroclusters. Phys. Chem. 2007, 9, 1676.
• C.G. Andrews, G. Bartoli, E. Marcantoni , M. Massaccesi: Borane-Pyridine.Encyclopedia of Reagents for Organic Synthesis 2007, John Wiley e Sons, Ltd, Chichester, UK, DOI: 101002/047084289X.rb.240.pub2.Article RB240.
• G. Bartoli, M. Bosco, A. Carlone , M. Locatelli , E. Marcantoni, P. Melchiorre, P. Palazzi, S. Sambri: A New , Mild, General and Efficient Route to Aryl Ethyl Carbonate in Solvent free Conditions promoted by Magnesium Perchlorate Eur. J. Org. Chem. 2006, 4429.
• G. Bartoli, R. Belleggia, S. Giuli, A. Giuliani, E. Marcantoni, M. Massaccesi, M. Paoletti "The CeCl3.7H2O/NaI system as promoter in the synthesis of functionalized trisubstituted alkenes via Knoevenagel condensation" Tetrahedron Lett. 2006, 47, 6501.
• G. Bartoli, M. Bosco, A. Carlone, M. Locatelli, E. Marcantoni, P. Melchiorre, L. Sambri "tert-Butyl Ethers: Renaissance of an Alcohol Protecting Group. Facile Cleavage with Cerium(III) Chloride/Sodium Iodide" Adv. Synth. Catal. 2006, 348, 905.
• E. Marcantoni, M. Massaccesi, M. Paoletti, L. Sambri "Diastereoselective synthesis of tertiary alcohols by nucleophilic addition to α-substituted-β-keto esters" ARKIVOC 2006,6, 49.
• G. Bartoli, R. Giovannini, A. Giuliani, E. Marcantoni, M. Massaccesi, P. Melchiorre, M. Paoletti, L. Sambri "Solvent-free Carbon-Oxygen bond formation catalysed by CeCl3.7H2O/NaI : Tetrahydropyranylation of hydroxy groups" Eur. J. Org. Chem. 2006, 1476.
• G. Bartoli, A. Giuliani, E. Marcantoni, M. Massaccesi, P. Melchiorre, S. Lanari, L. Sambri "Allylation of Aldehydes Promoted by the CeCl3.7H2O/NaI System: the Dependence of Regio- and Stereocontrol from the Reaction Conditions" Adv. Synth. Catal. 2005, 347, 1673.
• G. Bartoli, M. Bartolacci, A. Giuliani, E. Marcantoni, M. Massaccesi "Diastereoselective Lewis Acid Mediated Reductions of α-Alkyl-β-functionalised Carbonyl Compounds" Eur. J. Org. Chem. 2005, 2867. (An invited review-article)
• E. Marcantoni, G. Roselli, L. Lucarelli, G. Renzi, A. Filippi, C. Trionfetti, M. Speranza "The Crucial Role of Elusive ion-Dipole in the Gas-phase Electrophilic Aromatic Substitutions" J. Org. Chem. 2005, 70, 4133.
• G.Bartoli, M. Bosco, S. Giuli, A. Giuliani, L. Lucarelli, E. Marcantoni, L. Sambri, E. Torregiani "Efficient Preparation of 2-Indolyl-1-nitroalkane Derivatives Employing Nitroalkenes as Versatile Michael Acceptors: New Practical Linear Approach to Alkyl 9H-β-Carboline-4-carboxylate" J. Org. Chem. 2005, 70, 1941.
• G. Bartoli, M. Bosco, M. Locatelli, E. Marcantoni, P. Melchiorre, L. Sambri "Unusual and Unexpected Reactivity of t-Butyl Dicarbonate (Boc2O) with Alcohols in the Presence of Magnesium Perchlorate. A New and General Route to t-Butyl Ethers" Org. Lett. 2005,7, 427.
• G. Bartoli, M. Bartolacci, A. Giuliani, E. Marcantoni, M. Massaccesi, E. Torregiani "Improved Heteroatom Nucleophilic Addition to Electronpoor Alkenes Promoted by CeCl3.7H2O/NaI System Supported on Alumina in Solvent-free Conditions" J. Org. Chem. 2005, 70, 169.
• G. Bartoli, M. Bosco, E. Marcantoni, M. Massaccesi, S. Rinaldi, L. Sambri "Highly Diastereoselective Synthesis of β-Hydroxy Amides from β-Keto Amides" Synthesis 2004, 3092 (Practical Synthetic Procedures).
• G.Bartoli, M. Bosco, M. Locatelli, E. Marcantoni, M. Massaccesi, P. Melchiorre, L. Sambri "A Lewis Acid-Mediated Protocol for the Protection of Aryl Amines as their Boc-Derivatives" Synlett 2004, 1794.
• E. Marcantoni, R. Profeta, M. Petrini "Synthesis of Advanced Intermediates for the Preparation of Aza-analogues of pophyllotoxin" Tetrahedron Lett. 2004, 45, 2133.
• G. Bartoli, M. Bosco, G. Foglia, A. Giuliani, E. Marcantoni, L. Sambri "Solvent-free Indoles Addition to Carbonyl Compounds Promoted by CeCl3.7H2O/NaI-SiO2: an Efficient Method for the Synthesis of Streptindole" Synthesis 2004, 895.
• G. Bartoli, M. Bartolacci, M. Cortese, E. Marcantoni, M. Massaccesi, R. Pela, L. Sambri "Lewis Acid-Mediated Diastereoselective Reduction of N-Protected β-Amino Ketones: Influence of the Nature of Metal Atom and of Nitrogen Protecting Group" Eur. J. Org. Chem. 2004, 2359.
• G.Bartoli, M. Bosco, M. Locatelli, E. Marcantoni, P. Melchiorre, L. Sambri "Zn(ClO4)2.6H2O as a Powerful Catalyst for the Conversion of β-ketoesters into β-Enamino Esters" Synlett 2004, 239.
• G. Bartoli, M. Bosco, A. Giuliani, E. Marcantoni, A. Palmieri, M. Petrini, L. Sambri "Investigation into the Allylation Reactions of Aldehydes Promoted by CeCl3.7H2O/NaI System as Lewis Acid" J. Org. Chem. 2004, 69, 1290.
• G. Bartoli, M. Bosco, E. Marcantoni, P. Melchiorre, S. Rinaldi, L. Sambri "Highly Stereoselective Reduction of β-Keto Amides: The First General and Efficient Approach to N-mono- and non-Substituted anti-α-Alkyl-β-Hydroxy Amides" Synlett 2004, 73.
• G. Bartoli, E. Marcantoni, L. Sambri "The CeCl3.7H2O/NaI System in organic Synthesis: An efficient Water Tolerant Lewis Acid Promoter" Synlett 2003, 2101.
• G. Bartoli, M. Bosco, R. Dalpozzo, E. Marcantoni, M. Massaccesi, L. Sambri "Zn(ClO4)2.6H2O as a Powerful Catalyst for a Practical Acylation of Alcohols with Acid Anhydrides" Eur. J. Org. Chem. 2003, 4611.
• G. Bartoli, M. Bartolacci, M. Bosco, G. Foglia, A. Giuliani, E. Marcantoni, L. Sambri, E. Torregiani "The Michael Addition of Indoles to α,β-Unsaturated Ketones Catalyzed by CeCl3.7H2O/NaI Combination Supported on Silica Gel" J. Org. Chem. 2003, 68, 4594.
• G. Bartoli, M. Bosco, R. Dalpozzo, E. Marcantoni, M. Massaccesi, S. Rinaldi, L. Sambri "Mg(ClO4)2 as a Powerful Catalyst for the Acylation of Alcohols under Solvent Free Conditions" Synlett 2003, 39.
• G. Bartoli, M. Bosco, R. Dalpozzo, A. Giuliani, E. Marcantoni, T. Mecozzi, L. Sambri, E. Torregiani "An Efficient Procedure for the Preparation of (E)-α-Alkylidenecycloalkanones Mediated by CeCl3.7H2O/NaI System. Novel Methodology for the Synthesis of (S)-(-)Pulegone" J. Org. Chem. 2002, 67, 9111.
• M. Badioli, R. Ballini, M. Bartolacci, G. Bosica, E. Marcantoni, E. Torregiani "Addition of Organocerium Reagents to Morpholines Amides: Synthesis of Important Pheromone Components of Achaea janata" J. Org. Chem. 2002, 67, 8938.
• G. Bartoli, M. Bosco, E. Marcantoni, M. Massaccesi, S. Rinaldi, L. Sambri "LiClO4-acyl anhydrides complexes as powerful acylating reagents of aromatic compounds in solvent free conditions" Tetrahedron Lett. 2002, 43, 6331.
• E. Marcantoni, T. Mecozzi, M. Petrini "Allylation of Exocyclic N-Acyliminium Ions Generated from Chiral N-[1-(phenylsulfonyl)alkyl]oxazolidin-2-ones" J. Org. Chem. 2002,67, 2989.
• G. Bartoli, M. Bosco, E. Marcantoni, M. Petrini, L. Sambri, E. Torregiani "Conjugate Addition of Amines to α,β-Enones Promoted By CeCl3.7H2O/NaI System Supported in Silica Gel" J. Org. Chem. 2001, 66, 9052.
• G. Bartoli, M. Bosco, E. Marcantoni, M. Massaccesi, S. Rinaldi, L. Sambri "A Highly Diastereoselective TiCl4-Mediated Reduction of β-Hydroxy Ketones with BH3.py – A Very Efficient and General Synthesis of syn-1,3-diols" Eur. J. Org. Chem. 2001, 4679.
• G. Bartoli, G. Cupone, R. Dalpozzo, A. De Nino, L. Maiuolo, E. Marcantoni, A. Procopio "Cerium-Mediated Deprotection of Substituted Allyl Ethers" Synlett 2001, 1897.
• G. Bartoli, M. Bosco, R. Dalpozzo, E. Marcantoni, M. Massaccesi, S. Rinaldi, L. Sambri "One-pot highly stereoselective reduction of β-keto amides to syn-γ-aminols" Tetrahedron Lett. 2001, 42, 8811.
• R. Dalpozzo, A. De Nino, G. Bartoli, L. Sambri, E. Marcantoni "Organocerium reagents: A useful tool to alkylate carbonyls carrying strongly acidic hydrogen atoms" Recent Res. Devel. Organic Chem. 2001, 5, 181.
• G. Bartoli, M. Bosco, E. Marcantoni, M. Massaccesi, S. Rinaldi, L. Sambri "Highly stereoselective titanium-mediated addition of organocerium reagents to β-keto amides: an efficient synthesis of stereodefined β-hydroxy amides having a tertiary alcoholic fragment" Tetrahedron Letters 2001, 42, 6093.
• G. Bartoli, M. Bosco, E. Di Martino, E. Marcantoni, L. Sambri "Highly Stereoselective and Efficient Addition of Organocerium Reagents to syn-β-Alkyl-β-hydroxy-α-methyl Ketones by Way of Their Titanium Alkoxides – Synthesis of Complex 1,3-Diol Units with Three Stereodefined Centres" Eur. J. Org. Chem. 2001, 2901.
• G.Bartoli, M. Bosco, E. Marcantoni, M. Massaccesi, L. Sambri, E. Torregiani "Selective Deprotection of N-Boc-Protected tert-Butyl Ester Amino Acids by the CeCl3.7H2O/NaI System in Acetonitrile" J. Org. Chem. 2001, 66, 4430.
• A. Giardinà, E. Marcantoni, T. Mecozzi, M. Petrini "Claisen-Johnson Orthoester Rearrangement of γ-Hydroxy α,β-Unsaturated Ketones and Nitriles" Eur. J. Org. Chem. 2001, 713.
• R. Ballini, G. Bosica, E. Marcantoni, P. Vita, G. Bartoli "First TiCl4-Mediated Diastereoselective Reduction of α-Nitro Ketones to β-Nitro Alcohols by BH3.SMe2" J. Org. Chem. 2000, 65, 5854.
• G. Bartoli, M. C. Bellucci, M. Bosco, L. Sambri, R. Dalpozzo, E. Marcantoni "The Role of the α-Stereogenic Center in the Control of Stereoselection in the Reduction of α-Alkyl-β-hydroxy Ketones: A Highly Diastereoselective Protocol for the Synthesis of 1,2-syn-2-Alkyl-1,3-diols" Chem. Eur. J. 2000, 2590.
• G. Bartoli, M. C. Bellucci, E. Marcantoni, M. Petrini, L. Sambri, E. Torregiani "An Efficient Procedure for the Diastereoselective Dehydration of β-Hydroxy Carbonyl Compounds by CeCl3.7H2O/NaI System" Org. Lett. 2000, 2, 1791.
• G. Bartoli, M. C. Bellucci, M. Bosco, M. Massaccesi, E. Marcantoni, M. Petrini, L. Sambri "A Novel Route to the Vinyl Sulfide of Nine-Membered Macrocycle Moiety of Griseoviridin" J. Org. Chem. 2000, 65, 4553.
• G. Bartoli, M. C. Bellucci, M. Bosco, M. Di Deo, E. Marcantoni, L. Sambri, E. Torregiani "A Simple, Efficient, and General Method for the Conversion of Alcohols into alkyl Iodides by CeCl3.7H2O/NaI System in Acetonitrile" J. Org. Chem. 2000, 65, 2830.
• G. Bartoli, M. C. Bellucci, M. Bosco, L. Sambri, R. Dalpozzo, E. Marcantoni "TiCl4Mediated Reduction of 1,3-Diketones with BH3-pyridine Complex: a Highly Diastereoselective Method for the Synthesis of syn-1,3-Diols" Org. Lett. 2000, 2, 45.


1990 - 1999

• G. Bartoli, M. C. Bellucci, M. Bosco, A. Cappa, E. Marcantoni, L. Sambri, E. Torregiani "A Simple Method for the Selective Deprotection of p-Methoxybenzyl Ethers by Cerium(III) Chloride Heptahydrate and Sodium Iodide" J. Org. Chem. 1999, 64, 5696.
• R. Ballini, E. Marcantoni, S. Perrella "A Two Steps Synthesis of γ-Substituted and γ- Disubstituted α-(Alkyl)methylene-γ-butyrolactones" J. Org. Chem. 1999, 64, 2954.
• S. Alessandrini, G. Bartoli, M. C. Bellucci, R. Dalpozzo, M. Malavolta, E. Marcantoni, L. Sambri "Reversed Stereochemical Control of CeCl3 and TiCl4 in the Lewis Acid Mediated Reduction of α-Alkyl-β-keto Esters by Metal Hydrides. A General Methodology for the Diastereoselective Synthesis of erythro- and threo-α-Alkyl-β-hydroxy Esters" J. Org. Chem. 1999, 64, 1986.
• G. Bartoli, M. C. Bellucci, M. Bosco, R. Dalpozzo, E. Marcantoni, L. Sambri "Highly diastereoselective reduction of α-alkyl-β-hydroxy ketones with sodium and lithium boron hydrides via their titanium alcoholates" Tetrahedron Lett. 1999, 40, 2845.
• G. Bartoli, M. C. Bellucci, M. Bosco, E. Marcantoni, L. Sambri, E. Torregiani "Cerium(III) Chloride Catalyzed Michael Reaction of 1,3-Dicarbonyl Compounds and Enones in the Presence of Sodium Iodide Under Solvent Free Conditions" Eur. J. Org. Chem. 1999, 617.
• R. Giovannini, E. Marcantoni, M. Petrini "Claisen Rearrangement of γ-Hydroxyvinyl Sulfones via Ketene Acetal Derivatives. A New Entry to Functionalized (2E,4E)- Alkadienoic Esters" Tetrahedron Lett. 1998, 39, 5827.
• G. Bartoli, M. Bosco, R. Dalpozzo, A. De Nino, E. Marcantoni, L. Sambri "Synthesis of β,γ-Unsaturated Ketones via Cerium-Mediated Addition of Organolithium to Silylated Enaminones" J. Org. Chem. 1998, 63, 3745.
• G. Bartoli, M. Bosco, S. Cingolani, E. Marcantoni, L. Sambri "Efficient Diastereoselective Syntheses of erythro- or threo-α-Alkyl-β-hydroxy Sulfones by Reductions of α-Alkyl-β-keto Sulfones with TiCl4/BH3 or LiEt3BH/CeCl3, respectively" J. Org. Chem. 1998, 63, 3624.
• G. Bartoli, M. C. Bellucci, M. Bosco, E. Marcantoni, L. Sambri "Internal Lewis Acid Coordination as a Powerful Tool to Promote Highly Stereoselective Alkylation of α-Alkyl-β-hydroxy Ketones with Grignard Reagents" Chem. Eur. J. 1998, 4, 2154.
• G. Bartoli, M. Bosco, E. Marcantoni, L. Sambri, E. Torregiani "A Mild, Efficient, and Selective Method for the Desilylation of More Common Trialkylsilyl Ethers by Cerium(III) Chloride Heptahydride and Sodium Iodide in Acetonitrile" Synlett 1998, 209.
• G. Bartoli, M. Bosco, R. Dalpozzo, E. Marcantoni, L. Sambri "Opposite Stereochemical Effects Exerted by CeCl3 and TiCl4 on the Lewis Acid Mediated Reduction of α-Alkyl-β-ketophosphine Oxides. A Highly Stereoselective Protocol for the Synthesis of syn and anti α-Alkyl-β-hydroxyphosphine Oxides" Chem. Eur. J. 1997, 3, 1941.
• G. Bartoli, M. Bosco, E. Marcantoni, L. Sambri "1,2-Asymmetric Induction in the TiCl4 Mediated Alkylation of α-Methyl-β-silyloxy Ketones with Grignard Reagents" Tetrahedron Lett. 1997, 38, 3785.
• G. Bartoli, M. Bosco, E. Marcantoni, F. Nobili, L. Sambri "Cerium(III) Chloride, a Novel Reagent for Nonaqueous Selective Conversion of Dioxolanes to Carbonyl Compounds" J. Org. Chem. 1997, 62, 4183.
• R. Ballini, E. Marcantoni, E. Torregiani "The First Synthesis of (Z)-9,10- Epoxynonacosane, a New Long-Chain Epoxide Isolated from Stem Wax of Rubus Thibetanus" J. Nat. Prod. 1997, 60, 505.
• G. Bartoli, M. Bosco, E. Marcantoni, L. Sambri "TiCl4 Mediated LiBH4 reduction of β-Ketophosphine Oxides: a High Stereoselective Route to the Synthesis of anti-β- Hydroxyphosphine Oxides" Tetrahedron Lett. 1996, 37, 7421.
• R. Ballini, G. Bosica, E. Marcantoni "A new 1,4-Elimination of Benzenesulfinic Acid from β-Keto Phenylsulphones Via Their Tosylhydrazones" Tetrahedron 1996, 52, 10705.
• G. Bartoli, E. Marcantoni, M. Petrini, L. Sambri "A Stereoselective Synthesis of (E)- α,β-Unsaturated Ketones Involving the Reactions of Organocerium Reagents with Secondary β-Enamino Ketones" Chem. Eur. J. 1996, 2, 913.
• G. Bartoli, M. Bosco, J. Van Beek, L. Sambri, E. Marcantoni "Organo Cerium Reagents in Organic Chemistry: General Method of Synthesis of Alkyl Substituted 1,3-Diols by RLi-CeCl3 Addition to β-Hydroxyketones" Tetrahedron Lett. 1996, 37, 2293
• R. Ballini, E. Marcantoni, M. Petrini "Regioselective C-α' and C-β' Alkylation of Ketones Via α-Nitro Ketones: A New Synthesis of (±)-4-Methyl-3-heptanone, (±)- Phoracantholide, (±)-Dihydrorecifeiolide, and (±)-Muscone" Lieb. Annalen der Chemie 1995, 1381.
• R. Giovannini, E. Marcantoni, M. Petrini "Stereoselective Total Synthesis of (+)- Lentiginosine Using a Chiral Nitrone Intermediate" J. Org. Chem. 1995, 60, 5706.
• G. Bartoli, E. Marcantoni, L. Sambri, M. Tamburini "Cerium (III) Chloride promoted Nucleophilic Addition of Organolithium Reagents to α-Alkyl-β-Ketophosphine Oxides: A New Protocol for the Synthesis of Stereodefined Trisubstituted Olefins" Angew. Chem., Int. Ed. Engl. 1995, 34, 2046.
• E. Marcantoni, M. Petrini, O. Polimanti "Oxidation of Secondary Amines to Nitrones Using Urea-Hydrogen Peroxide Complex (UHP) and Metal Catalyst" Tetrahedron Lett. 1995,36, 3561.
• G. Bartoli, C. Cimarelli, E. Marcantoni, G. Palmieri, M. Petrini "Chemo- and Diastereoselective Reduction of β-Enamino Esters: A Convenient Synthesis of Both cis- and trans-γ-Amino Alcohols and γ-Amino Esters" J. Org.Chem. 1994, 59, 5328.
• G. Bartoli, M. Bosco, L. Sambri, E. Marcantoni "Cerium (III) Chloride Mediated Michael Addition of RMgX to Nitroenes: a Very Efficient Access to Complex Nitroalkanes" Tetrahedron Lett. 1994, 35, 8651.
• G. Bartoli, L. Sambri, E. Marcantoni, M. Petrini "Cerium Chloride (III) promoted Nucleophilic Addition of Organolithium Reagents to α-Diphenylphosphinoyl Ketones. An efficient Method for the Synthesis of Horner Wittig Intermediates" Tetrahedron Lett. 1994, 35, 8453.
• G. Bartoli, C. Cimarelli, E. Marcantoni, G. Palmieri, M. Petrini "Highly Stereoselective Synthesis of α,β-Unsaturated Ketones by CeCl3 Mediated Addition of Grignard Reagents to β-Enamino Ketones" J.Chem.Soc. Chem. Comm. 1994, 715.
• G. Bartoli, E. Marcantoni, M. Petrini "Cerium (III) Chloride Mediated addition of Grignard Reagents on Nitroalkanes: Synthesis of N,N-Disubstituted Hydroxylamines" J.Chem.Soc.Chem.Comm. 1993,1373.
• G. Bartoli, E. Marcantoni, M. Petrini "Cerium (III) Chloride Mediated Addition of Grignard Reagents to 1,3-Diketones" Angew. Chem. Int. Ed. Engl. 1993, 32, 1061.
• R. Ballini, G. Bartoli, R. Giovannini, E. Marcantoni, M. Petrini "Retro Claisen Cleavage of α-Nitrocycloalkanones Using Trimethylsilylmethylmagnesium Chloride (Peterson Reagent): Synthesis of functionalized β-Ketotrimethylsilanes" Tetrahedron Lett. 1993, 34, 3301.
• R. Ballini, G. Bartoli, P.V. Gariboldi, E. Marcantoni, M. Petrini "Reactivity of α- Nitroketones towards Organometallic Reagents: Straightforward Synthesis of Tertiary β-Nitroalkanols" J. Org. Chem. 1993, 58, 3368.
• R. Ballini, R. Castagnani, E. Marcantoni "A Novel, Chemoselective, ‘One-pot’ Procedure for the Simultaneous Denitration-Deoxygenation of 2-Nitroketones by TsNHNH2-NaBH4" J. Chem. Soc., Perkin Trans. 1 1992, 3161.
• R. Ballini, E. Marcantoni, M. Petrini "Synthesis of Functionalized Nitroalkanes by Oxidation of Oximes with Urea-Hydrogen Peroxide Complex and Trifluoroacetic Anhydride" Tetrahedron Lett. 1992, 33, 4835.
• G. Bartoli, E. Marcantoni, M. Petrini "Nitrones from Addition of Benzyl and Allyl Grignard Reagents to Alkyl Nitro Compounds: Chemo-, Regio-, and Stereoselectivity of the Reaction" J. Org. Chem. 1992, 57, 5834.
• R. Ballini, G. Bartoli, R. Castagnani, E. Marcantoni, M. Petrini "Direct a’Alkylation of 2- Nitro Ketone Dianions" Synlett 1992, 1, 64.
• R. Ballini, E. Marcantoni, M. Petrini "α-Nitroalcohols as Precursors of Aldehydes ω- Functionalized: a New Synthesis of 7-Acetoxyheptanal, 7-(2-Tetrahydropyranyloxy) heptanal and 8-(2-Tetrahydropyranyloxy)octanal" Synth. Comm. 1992, 22, 641.
• R. Ballini, E. Marcantoni, M. Petrini "A Nitrone-Based Approach to the Enantioselective Total Synthesis of (-)-Anisomycin" J. Org. Chem. 1992, 57, 1316.
• G. Bartoli, M. Bosco, R. Dalpozzo, E. Marcantoni, G. Palmieri "Reactivity of Nitro- and Nitro-arenes with Vinyl Grignard Reagents: Synthesis of 2-(Trimethylsilyl)indoles" J. Chem. Soc., Perkin Trans. 1 1991, 2757.
• R. Ballini, E. Marcantoni, M. Petrini "An Improved and Simple Synthesis of Methyl or Ethyl 7-Oxoheptanoate and 7-Acetoxyheptanal" Synth Comm. 1991, 21, 1075.
• R. Ballini, E. Marcantoni, M. Petrini "Enantioselective Synthesis of the Lactone Moiety of the Mevinic Acids using D-Xylose as a Chiral Precursor" J. Chem. Soc., Perkin Trans. 1 1991, 490.
• G. Bartoli, E. Marcantoni, M. Petrini "Enantioselective Synthesis of Nitrogen Derivatives by Allyl Grignard Addition on Optically Active Nitroalkanes" J. Chem. Soc., Chem. Commun. 1991, 793.
• G. Bartoli, M. Bosco, R. Dalpozzo, E. Marcantoni "Reactivity of acylsilane phenyl- hydrazones with phophorus trichloride" Tetrahedron Letters 1990, 31, 6935.
• G. Bartoli, M. Petrini, E. Marcantoni, M. Bosco, R. Dalpozzo "A new rearrangement of nitrones: acid promoted conversion of vinylnitrones into N-(g-ketoalkyl)-N- phenylhydroxylamines" Tetrahedron Letters 1990, 31, 6089.
• L. Barboni, G. Bartoli, E. Marcantoni, M. Petrini,R. Dalpozzo "N-allylhydroxylamines from 1,2-addition of allyl Grignard reagents to nitro compounds: generality and drawbacks of the reaction" J. Chem. Soc. Perkin Trans. 1 1990, 2133.
• G. Bartoli, E. Marcantoni, M. Petrini, R. Dalpozzo "Reaction of aryl and alkyl nitro compounds with 2-butenylmagnesiumchloride: synthesis of a new class of nitrones" J. Org. Chem. 1990, 55, 4456.

1980 - 1989

• R. Ballini, E. Marcantoni, M. Petrini "A new general synthesis of sulfones from alkyl or aryl halides and p-toluenesulfohydrazide" Tetrahedron 1989, 45, 6791.
• R. Ballini, G. Bartoli, M. Bosco, R. Dalpozzo, E. Marcantoni "Alkylation orientation rules in conjugate addition of Grignard reagents to nitropyrrole and nitrothiophene systems" Tetrahedron 1988, 44, 6435.
• R. Ballini, E. Marcantoni, M. Petrini, G. Rosini "A new oxidative cleavage of 2-nitrocycloalkanones by hydrogen peroxide: an important, efficient method for dicarboxylic acid or ketoacid synthesis" Synthesis 1988, 915.
• G. Bartoli, E. Marcantoni, M. Bosco, R. Dalpozzo "Unexpected reactivity of allyl magnesium chloride with nitroarenes. A general method of synthesis of N-allyl -N- arylhydroxylamines and N-allylanilines" Tetrahedron Lett. 1988, 29, 2251.
• R. Ballini, M. Petrini, E. Marcantoni, G. Rosini "Utilization of basic alumina in a One- Pot synthesis of 1,4-diketones, 1,4,7-triketones and dihydrojasmone by conjugate addition of nitroalkanes to enones" Synthesis 1988, 231.
• M. Petrini, R. Ballini, G. Rosini, E. Marcantoni "Amberlyst 15: a pratical catalyst for methyl esterification of carboxylic acids" Synthetic Commun. 1988, 18, 847.





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